Forensic Medicine · Forensic Toxicology (General, Organophosphorus, Corrosives, Metals, Narcotics, Alcohol)

A forensic autopsy reveals a well-demarcated, leathery eschar around the lips and chin of a suicide victim who ingested an industrial acid. The eschar has a distinct yellow-brown colour. Which corrosive was most likely ingested?

  • A Nitric acid
  • B Sulfuric acid
  • C Hydrochloric acid
  • D Carbolic acid (phenol)
Correct answer: A. Nitric acid

Explanation

Nitric acid produces a characteristic yellow eschar because the acid reacts with tissue proteins through the xanthoprotein reaction, nitrating aromatic amino acids such as tyrosine. Sulfuric acid gives a black or dark brown eschar, hydrochloric acid a whitish to grey-brown eschar, and phenol a soft whitish eschar with its characteristic carbolic odour. The colour of the eschar therefore directly identifies the acid.

Reference: Parikh's Textbook of Medical Jurisprudence, Forensic Medicine and Toxicology, 6th ed.

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