Forensic Medicine · Forensic Toxicology (General, Organophosphorus, Corrosives, Metals, Narcotics, Alcohol)

A suspected opioid overdose victim is brought dead. Which postmortem sample would be MOST suitable for toxicological confirmation of heroin (diacetylmorphine) use, given that heroin is rapidly hydrolysed to 6-monoacetylmorphine (6-MAM) and then to morphine?

  • A Central blood — most representative of circulating drug levels
  • B Gastric contents for unchanged diacetylmorphine if ingested
  • C Urine or vitreous for 6-MAM, which persists longer than heroin in biological fluids
  • D Liver tissue for cytochrome P450 metabolite profiling
Correct answer: C. Urine or vitreous for 6-MAM, which persists longer than heroin in biological fluids

Explanation

6-Monoacetylmorphine (6-MAM) is the specific metabolite of heroin that is NOT formed from any other opiate; its presence in urine, vitreous, or blood specifically indicates heroin (not just morphine or codeine) use. Heroin itself has a plasma half-life of approximately 2–3 minutes; 6-MAM has a half-life of approximately 20–30 minutes. In postmortem specimens, urine has the highest 6-MAM yield due to renal concentration, but vitreous 6-MAM detection is valuable given the protected nature of vitreous from redistribution. Central blood may show only morphine, masking the heroin-specific evidence.

Reference: The Essentials of Forensic Medicine and Toxicology (Narayan Reddy), 34th ed.

High-yield for: NEET PGINI-CETNExTFMGEUSMLEPLABMRCP

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