Biochemistry · TCA Cycle and ETC (Bioenergetics, Oxidative Phosphorylation)

MELAS syndrome (Mitochondrial Encephalomyopathy, Lactic Acidosis, Stroke-like episodes) is caused by mtDNA mutations. The metabolic consequence of ETC dysfunction that DIRECTLY causes lactic acidosis is:

  • A Excess acetyl-CoA from impaired TCA cycle overflows into ketogenesis
  • B Proton leak across the inner mitochondrial membrane acidifies the cytoplasm
  • C Blocked NADH oxidation by impaired ETC causes NADH/NAD+ ratio to rise, forcing pyruvate → lactate via LDH to regenerate NAD+
  • D Impaired gluconeogenesis in mitochondria causes glucose deficiency
Correct answer: C. Blocked NADH oxidation by impaired ETC causes NADH/NAD+ ratio to rise, forcing pyruvate → lactate via LDH to regenerate NAD+

Explanation

Defective ETC (complex I most commonly in MELAS — m.3243A>G mutation in mt-tRNA-Leu) cannot oxidize NADH to NAD+. Elevated NADH/NAD+ ratio inhibits TCA cycle dehydrogenases (isocitrate, alpha-ketoglutarate, malate dehydrogenase) — effectively blocking the TCA cycle — and forces pyruvate reduction to lactate via lactate dehydrogenase to regenerate the NAD+ needed for continued glycolysis. This is why mitochondrial disease causes type B lactic acidosis (not type A from hypoxia/ischemia) — lactate/pyruvate ratio is elevated (>20), and the acidosis occurs without tissue hypoperfusion.

Reference: Harper's Illustrated Biochemistry, 32nd ed.

High-yield for: NEET PGINI-CETNExTFMGEUSMLEPLABMRCP

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