Biochemistry · Lipid Chemistry (Sphingolipids, Eicosanoids, Ketogenesis)

During prolonged starvation, the brain adapts to use ketone bodies as fuel. Which enzyme in extrahepatic tissues is required to activate acetoacetate before it can enter the TCA cycle?

  • A Succinyl-CoA:3-ketoacid CoA transferase (SCOT)
  • B Acetoacetyl-CoA thiolase
  • C HMG-CoA synthase
  • D Acetyl-CoA carboxylase
Correct answer: A. Succinyl-CoA:3-ketoacid CoA transferase (SCOT)

Explanation

SCOT (thiophorase) transfers CoA from succinyl-CoA to acetoacetate, forming acetoacetyl-CoA, which thiolase then splits into two acetyl-CoA for the TCA cycle. This enzyme is absent in the liver, so liver produces but cannot utilize ketone bodies. HMG-CoA synthase and thiolase are part of ketogenesis in liver.

Reference: Harper's Illustrated Biochemistry, 32nd ed.

High-yield for: NEET PGINI-CETNExTFMGEUSMLEPLABMRCP

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