Biochemistry · Free Radicals, Antioxidant Defence and Xenobiotic Metabolism

Phenobarbital is a classic inducer of cytochrome P450 enzymes. Through which nuclear receptor does phenobarbital-mediated CYP3A4/CYP2B6 induction primarily occur?

  • A AhR (aryl hydrocarbon receptor) — a ligand-activated transcription factor in the cytosol
  • B CAR (constitutive androstane receptor) — phenobarbital indirectly activates CAR, which heterodimerises with RXR to drive CYP expression
  • C PXR (pregnane X receptor) — the primary receptor for all drug-mediated CYP induction
  • D PPAR-alpha (peroxisome proliferator-activated receptor) — mediates fibrate-induced CYP4A induction
Correct answer: B. CAR (constitutive androstane receptor) — phenobarbital indirectly activates CAR, which heterodimerises with RXR to drive CYP expression

Explanation

Phenobarbital induces CYP2B6 and CYP3A4 primarily through the Constitutive Androstane Receptor (CAR). Interestingly, phenobarbital does not directly bind CAR; instead it indirectly promotes CAR nuclear translocation by inhibiting its cytoplasmic anchoring via RACK1/protein phosphatase 2A. Nuclear CAR heterodimerises with RXR and binds phenobarbital response elements (PBRem) in CYP gene promoters. AhR mediates induction of CYP1A1/1A2 by polycyclic aromatic hydrocarbons. PXR mediates induction by rifampicin and St. John's Wort (CYP3A4). PPAR-alpha mediates fatty acid-responsive CYP4A induction.

Reference: Harper's Illustrated Biochemistry, 32nd ed.

High-yield for: NEET PGINI-CETNExTFMGEUSMLEPLABMRCP

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