Biochemistry · Carbohydrate Metabolism (Glycolysis, Gluconeogenesis, Glycogen, HMP Shunt)

Glycogenin is a key protein in glycogen metabolism. Which statement accurately describes its function?

  • A It adds glucose residues from UDP-glucose to the non-reducing ends of glycogen, extending the chain
  • B It self-glucosylates to form a short glucose primer covalently attached to its tyrosine residue, which glycogen synthase then extends
  • C It catalyzes the formation of alpha-1,6 branch points in glycogen
  • D It phosphorylates glycogen phosphorylase to initiate glycogenolysis
Correct answer: B. It self-glucosylates to form a short glucose primer covalently attached to its tyrosine residue, which glycogen synthase then extends

Explanation

Glycogenin acts as both enzyme and substrate: it uses UDP-glucose to self-glucosylates a tyrosine residue, creating a short primer of about 8 glucose residues. Glycogen synthase then extends this chain. Option A describes glycogen synthase. Option C describes branching enzyme. Option D is incorrect, as glycogenin has no kinase activity.

Reference: Lehninger Principles of Biochemistry, 8th ed.

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